I believe I understand your question B2B (over the years of diving, I have learned to try and understand the intent of divers' questions in regards to areas/subjects they are new in researching). If a diver mistakenly received a tank with EAN50 (approximately 50% Oxygen and 50% Nitrogen) and they didn't check it and didn't have an analyzer, I do not believe a diver would readily know the mixture had such a high O2 content just by breathing it from a regulator.For example what would happen to a diver if accidentally the fill in there Nitrox tank was 50% Nitrox and 50% Air ?? and they didn’t test it or have it tested with an analyzer. would the diver be able to tell, would it taste funny in there mouth ? what could possibly happen.
But for a diver to mistakenly receive that mix and actually dive it, a number of mistakes, not just one would likely have to occur. It would have to be a break down in the system which would mean there were errors from many different sources including diver error. It's not that it can't happen, however. So check, check, and recheck.
We have had a number of recent threads regarding Enriched Air (commonly referred to as Nitrox). I'll find them and link them shortly for your reference.